A 22,000μF at 25-volt Capacitor is the correct value.
The Positive Capacitor Terminal connects to the B+ terminal on the regulators, and the Negative terminal connects to Frame/Battery Ground
The Caps Labeled #14 in the diagram are mislabeled as 1μF and should be 22,000μF.
A 25-volt cap will be sufficient. 80v on a 12v system will be overkill and will be significantly larger in size.
A 25v Cap operating at less than 16 volts is already reasonably/safely over-rated.
80v might not be needed but as it will not improve, but also, not degrade anything. If it makes you sleep better, so be it!
The 1μF Cap labeled #22 is also correct. It is for Radio Frequency (RF) Noise suppression of the electric Fuel Pump.
The diagram shows Two Capacitors.
One for each Generator, items #5 and #10.
If you do not have the Secondary/External #10 Generator installed, you will only have One Cap #14 on the Primary Generator #5.
The reason for two Caps is because they need to be located close to the Generators/Regulators and before any Switches or fuses.
If you only had one Cap installed at the primary Regulator, and the Secondary Generator was to be isolated from the Battery, its regulator would not see a load and you would risk damaging the unloaded regulator.
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It is interesting to note that neither Capacitor is needed nor performs any function as long as the Generators are connected to the Battery.
So 99.999% of the time they do nothing. They are just $10 insurance policies for the $300 Regulators.
This is why every now and then someone will declare that they have been flying for years without a Cap and never have a problem.